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CAS NO.867-13-0
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quick details of Triethyl phosphonoacetate raw liquids
Product Name Triethyl phosphonoacetate
CAS 867-13-0
MF C8H17O5P
MW 224.19
EINECS 212-757-6
MOL File 867-13-0.mol
Chemical Properties
Melting point -24°C
Boiling point 142-145 °C9 mm Hg(lit.)
Density 1.13 g/mL at 25 °C(lit.)
refractive index n20/D 1.431(lit.)
Flash point 165°C
storage temp. Keep in dark place,Sealed in dry,Room Temperature
color: Clear
Specific Gravity 1.130
Water Solubility Slightly miscible with water.
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Triethyl phosphonoacetate is used for Horner-Emmons modification.
Uses
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
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