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CAS NO.22722-98-1
Product Name: | Sodium bis(2-methoxyethoxy)aluminiumhydride |
CAS: | 22722-98-1 |
MF: | C6H16AlNaO4 |
MW: | 202.16 |
EINECS: | 245-178-2 |
Boiling point | 396-402°C |
density | 1.036 g/mL at 25 °C |
vapor pressure | 21 mm Hg ( 20 °C) |
Fp | 40 °F |
storage temp. | Flammables area |
solubility | Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons. |
form | Viscous Liquid |
Specific Gravity | 1.036 |
color | Clear to slightly hazy, colorless to light amber |
explosive limit | 7% |
Water Solubility | reacts |
Sensitive | Air & Moisture Sensitive |
Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
Merck | 14,8564 |
Exposure limits | ACGIH: TWA 20 ppm OSHA: Ceiling 300 ppm; TWA 200 ppm NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) |
InChIKey | OKUDBXZACZBZJE-UHFFFAOYSA-N |
LogP | -2.64 at 25℃ and pH7 |
Uses | Reducing agent. |
Uses | Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines. |
Uses | Red-Al sodium bis(2-methoxyethoxy)aluminum hydride can be used as:
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