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Country: China (Mainland)
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CAS NO.1070-89-9
Product Name: | Sodium bis(trimethylsilyl)amide |
CAS: | 1070-89-9 |
MF: | C6H18NNaSi2 |
MW: | 183.37 |
EINECS: | 213-983-8 |
Melting point | 171-175 °C (lit.) |
Boiling point | 67°C |
density | 0.904 g/mL at 25 °C |
Fp | 43 °F |
storage temp. | 2-8°C |
solubility | Soluble in hexane, toluene, ether,terahydrofuran, benzene and toluene. |
form | Liquid |
Specific Gravity | 0.9 |
color | Clear orange to brown |
Water Solubility | reacts |
Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
Sensitive | Moisture Sensitive |
BRN | 3629917 |
Uses | Sodium bis(trimethylsilyl)amide is a synthetically useful reagent in that it combines both high basicity and nucleophilicity, each of which may be exploited for useful organic transformations such as selective formation of enolates, preparation of Wittig reagents, formation of acyl anion equivalents, and the generation of carbenoid species. As a nucleophile, it has been used as a nitrogen source for the preparation of primary amines.It is useful as a sterically hindered base and as a nucleophile. |
Uses | It is a strong base; deprotonates ketones and esters to generate enolate derivative. |
Uses | Significantly accelerated the polymerization of pheneylacetylene in conjunction with rhodium (I) catalysis |
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Wuhan Han Sheng New Material Technology Co. Ltd is a professional company which specialized in manufacturing and selling chemical raw materials, chemical products, pharmaceutical intermediates, veterinary medicine intermediates, dye intermediates, pigments, cosmetics raw materials and chemical reagents.
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